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典型矿山固废充填材料有害气体释放机制与控制技术研究进展

Recent advances in hazardous gas emission mechanisms and control technologies for typical mine solid waste backfill materials

  • 摘要: 随着工业化和全球经济的持续发展,矿业开采及工业活动产生了大量固体废弃物,其处置问题日益严峻。这类大宗固废不仅占用土地资源、污染环境,还加剧了自然资源的紧张局势,推动其资源化与循环利用已成为迫切需求。固废充填开采作为一种绿色低碳的关键技术,既可有效解决固废堆存难题,又能实现采空区治理、防止地表塌陷等地质灾害,为大宗固废处置与矿山环境修复提供了重要路径。然而,固废充填材料本身成分复杂,在充填过程中可能与添加剂、微生物及周围环境因子发生耦合作用,诱发一系列复杂的物理化学反应,进而释放硫化氢(H2S)、二氧化硫(SO2)、氮氧化物(NOx)、氨气(NH3)和氟化氢(HF)等具有毒性或可燃性的有害气体,对生态环境与矿区作业安全构成潜在风险。因此,如何有效控制和减少有害气体释放,确保固废充填材料在采空区中的环境安全性,已成为固废充填开采亟待突破的关键技术难题之一。本研究聚焦于煤基固废、磷化工固废和尾矿砂等典型矿山充填材料,系统分析其物理化学特性及有害气体的释放机制与主要影响因素,梳理当前控制技术的研究进展与工程应用。研究成果可为固废充填材料的环境安全利用提供理论依据与技术支撑,推动其在采空区治理中的绿色化、高效化与可持续发展,同时为相关领域的后续研究提供思路参考。

     

    Abstract: With the advancement of industrialization and the global economy, the disposal of a substantial volume of solid waste generated by mining and industrial activities has emerged as a critical issue. These bulk solid wastes occupy land, contaminate the environment, and with the progressive depletion of natural resources, the realization of their resource utilization and recycling has become an urgent matter. Solid waste backfilling mining is a key technology in green and low-carbon mining. It can not only address the problem of solid waste disposal but also manage goafs and prevent geological disasters such as ground subsidence, providing an effective approach for the disposal of bulk solid wastes and the governance of goafs. Nevertheless, when solid wastes are employed as backfill materials, they interact with the surrounding environment and may release harmful gases such as hydrogen sulfide (H2S), sulfur dioxide (SO2), nitrogen oxides (NOx), ammonia (NH3), and hydrogen fluoride (HF), which not only pollute the environment but also pose a threat to the safe production during the mining backfilling process. Therefore, how to effectively control and reduce the release of hazardous gases has become one of the key technical challenges in solid waste backfilling mining. This research focuses on typical mining backfill materials, such as coal-based solid wastes, phosphorus chemical solid wastes, and tailings sands, systematically investigates their material characteristics, as well as the mechanisms and influencing factors of harmful gas release, and summarizes the current technologies and methods for controlling harmful gases. The aim is to offer theoretical and technical support for the safe application of solid waste backfill materials, promote the rational utilization and sustainable development of solid wastes in the treatment of goafs, and provide directions and ideas for subsequent studies.

     

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