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多气体组分环境下原位保压煤样瓦斯压力衰减特性及演化规律

Gas pressure attenuation characteristics and evolution law of in-situ pressure preservation coal samples under multi-gas component environment

  • 摘要: 深部煤层原位瓦斯压力的精确测定对煤矿安全生产至关重要。然而传统取心测压技术,较少考虑煤层内气体成分的复杂性,忽略了取心过程中煤样自由体积的扩张对原位瓦斯压力的影响,从而降低原位瓦斯压力测定的准确性。基于深部煤层保压保瓦斯取心技术理念,聚焦于取心后煤样自由体积扩张导致的瓦斯压力重平衡过程,自主研发原位保压煤样多气体组分解吸系统,系统开展了多气体组分环境下的保压煤样解吸试验,揭示了不同气体组分对原位瓦斯压力动态演化的影响机制。结果表明:① 保压取心整个过程中瓦斯压力变化可分为初始吸附平衡阶段、变体积阶段和解吸平衡阶段,而变体积阶段是瓦斯压力变化的主要阶段,压力衰减速率随体积扩张逐渐减小;② 瓦斯压力变化受取心体积扩张程度、初始吸附量及气体竞争吸附的共同影响,自由体积扩张将导致气体分子间平均自由程增加,进而减弱了分子间的碰撞频率与强度,促使瓦斯压力下降;③ 强吸附性气体(如CO2)的存在对保压煤样的瓦斯压力衰减具有缓冲作用,而弱吸附性气体(如N2)则加速瓦斯压力下降;④ 保压煤样取心过程中,CO2的竞争吸附特性显著调控瓦斯压力的变化,CH4主导初期瓦斯压力变化,N2在低压阶段解吸量增加。研究结果可为深部煤层保压取心瓦斯压力准确获取提供一种新方法,为煤矿瓦斯抽采达标评判和防突措施效果检验提供技术支撑。

     

    Abstract: Accurate determination of in-situ gas pressure in deep coal seams is crucial to the safe production of coal mines. However, the traditional coring and pressure measurement techniques do not take into account the complexity of the gas composition in the coal seam and ignore the effect of the expansion of the free volume of the coal samples on the in-situ gas pressure during the coring process, which reduces the accuracy of the in-situ gas pressure measurement. Based on the concept of pressure-preserving gas coring in deep coal seams and focusing on the gas pressure rebalancing process caused by the expansion of the free volume of coal samples after coring, we independently developed a multi-gas component desorption system for in-situ pressure-preserving coal samples, and systematically carried out pressure-preserving coal sample desorption experiments under a multi-gas component environment, which reveals the mechanism of the influence of different gas components on the dynamic evolution of the in-situ gas pressure. The results show that: ① the gas pressure change during the whole process of fidelity coring can be divided into the initial adsorption equilibrium stage, the variable volume stage and the desorption equilibrium stage, while the variable volume stage is the main stage of the gas pressure change, and the rate of pressure decay decreases gradually with the expansion of the volume; ② the change of the gas pressure is affected by the degree of expansion of the coring volume, the initial adsorption amount and the gas competition for adsorption, and the expansion of the free volume will result in the The free volume expansion will lead to an increase in the mean free range of gas molecules, which will weaken the frequency and intensity of intermolecular collisions and contribute to the decrease of gas pressure; ③ The presence of strongly adsorbable gases (e.g., CO2) has a buffering effect on the decay of gas pressure in the pressure-retaining coal samples, whereas the weakly adsorbable gases (e.g., N2) accelerated the decrease of gas pressure; ④ In the process of the pressure-retaining coal samples coring, the competitive adsorption characteristics of CO2 significantly modulate the change of gas pressure, and CH4 dominated the initial gas pressure change, with CH4 dominating the initial gas pressure. change, CH4 dominates the initial gas pressure change, and N2 desorption increases in the low-pressure stage. The results of this study can provide a new method for accurately obtaining the gas pressure in deep coal seams by pressure preservation coring, and provide technical support for judging the gas extraction standard and checking the effect of anti-surge measures in coal mines.

     

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